catena-Poly[[chloridocopper(I)]-μ-η2,σ1-3-(2-allyl-2H-tetra­zol-5-yl)pyridine]

نویسنده

  • Wei Wang
چکیده

The title compound, [CuCl(C(9)H(9)N(5))](n), prepared by solvo-thermal synthesis, is a new homometallic Cu(I)-olefin coordination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetra-zol-5-yl)pyridine ligands and are each bonded to one terminal Cl atom. The organic ligand acts as a bidentate ligand bridging two neighboring Cu centers through the bonds to the N atom of the pyridine ring and the double bond of the allyl group. Weak Cu⋯Cl [3.136 (8) Å), C-H⋯Cl and C-H⋯N inter-actions connect the coordination polymers into a three-dimensional structure.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008